This seems like a handy way to confirm email addresses when a user signs up to your service.
If it returns false, send a regular "confirm your email" email.
Firefox's BrowserID/Persona used to do something similar. If you were logged into an email account (which supported it) and you signed up for a site (which supported it), it would auto-confirm your email. I never saw it in the wild, but the demo was awesome.
I wish browsers found an easy, secure way to bake this into the product. I'd much rather a confirmation modal than having to go to your email and click a link.
It depends on why you're checking emails. If it's just for password recovery, for example, then it's the user's loss if they intentionally use an invalid email.