That's really what "defund the police" does. The police union has a toxic contract with the police department. By dissolving the counterparty of the contract, you remove it from the equation. New law enforcement agencies can start from scratch without the weight of either the contract or, initially, any of the problematic personnel.
So having seen many ground up rewrites of code I have to ask how do we make sure that when we redo the police we avoid the problems we got this time around?
Police toxicity is a path-dependent phenomenon. We got here by decades of incrementalism, where politicians, many of whom were, at the time, avowed racists, agreed to various aspects of civilian-police relations. Simply starting over today with current civilian leadership to draft a new doctrine guarantees a dramatically different outcome.