If they were to make the copy available for everyone through their own syndicator then sure, but they don't. The "copy" is only available for the original reader, who had legitimate access to the original anyway.
Under copyright, you're allowed to make full copies of works which you have legitimate access to, as long as you don't distribute them to others.
Edit: They have more details here: https://help.getpocket.com/article/929-pocket-premium-perman...
Permanent library means they make copies of the articles and links that you save, so they are available even if the original goes down.