No, CGNAT (Carrier-Grade NAT - https://en.wikipedia.org/wiki/Carrier-grade_NAT) is an IPv4 only thing. https://www.rfc-editor.org/rfc/rfc6598 specifies they should use 100.64.0.0/10 for it, to avoid conflicting with the pre-existing private-use ranges. IPv6 removes the need for using CGNAT, as each home router is allocated a public IP (rather than a CGNAT IP) on its public link.
No, CGNAT has absolutely nothing to do with IPv6. CGNAT is nothing more than ISPs not providing a public IP to the gateway on your LAN (i.e. your router). To avoid conflicts with existing ranges, a new ranges for that purpose was allocated. There are different technologies to enable IPv4<->IPv6, none of which care about the existence of CGNAT.